Production, isolation and spectroscopic studies of the endohedral fullerene Sc2@C80 (I-III)--颗粒学报PARTICUOLOGY

Wang, C., Gan, L., Bai, C., & Shinohara, H. (2004). Production, isolation and spectroscopic studies of the endohedral fullerene Sc2@C80 (I-III). China Particuology, 2(5), 189-191. https://doi.org/10.1016/S1672-2515(07)60056-6

Production, isolation and spectroscopic studies of the endohedral fullerene Sc₂@C₈₀ (I-III)

Chunru Wang ^{a b *}, Lihua Gan ^a, Chunli Bai ^a, Hisanori Shinohara ^b

a Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China
b Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan

10.1016/S1672-2515(07)60056-6

Volume 2, Issue 5, October 2004, Pages 189-191

Received 17 June 2004, Accepted 25 July 2004, Available online 27 November 2007.

E-mail: crwang@iccas.ac.cn

Highlights

Abstract

The isolation of multiple-isomers of Sc₂@C₈₀ (I, II, III) endohedral metallofullerenes is reported for the first time. The new C₈₀-based Sc-metallofullerenes are characterized by UV-Vis-NIR absorption spectroscopy and detailed chromatographic retention time data. A close relationship between the isomer structure and the corresponding HPLC retention time of the metallofullerenes is presented.

Graphical abstract

Keywords

fullerenes; endohedral metallofullerenes; super-conductivity

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