Modeling heterogeneous chemical processes on aerosol surface--颗粒学报PARTICUOLOGY

Deng, J., Wang, T., Liu, L., & Jiang, F. (2010). Modeling heterogeneous chemical processes on aerosol surface. Particuology, 8(4), 308-318. https://doi.org/10.1016/j.partic.2009.12.003

Modeling heterogeneous chemical processes on aerosol surface

Junjun Deng ^a, Tijian Wang ^a *, Li Liu ^{a b}, Fei Jiang ^a

a School of Atmospheric Sciences, Nanjing University, 22 Hankou Road, Nanjing 210093, China
b Guizhou Institute of Mountainous Climate and Environment, Guiyang 550002, China

10.1016/j.partic.2009.12.003

Volume 8, Issue 4, August 2010, Pages 308-318

Received 23 December 2008, Revised 16 November 2009, Accepted 16 December 2009, Available online 28 April 2010.

E-mail: tjwang@nju.edu.cn

Highlights

Abstract

To explore the possible impact of heterogeneous chemical processes on atmospheric trace components, a coupled box model including gas-phase chemical processes, aerosol thermodynamic equilibrium processes, and heterogeneous chemical processes on the surface of dust, black carbon (BC) and sea salt is set up to simulate the effects of heterogeneous chemistry on the aerosol surface, and analyze the primary factors affecting the heterogeneous processes. Results indicate that heterogeneous chemical processes on the aerosol surface in the atmosphere will affect the concentrations of trace gases such as H₂O₂, HO₂, O₃, NO₂, NO₃, HNO₃ and SO₂, and aerosols such as SO₄²⁻, NO₃⁻ and NH₄⁺. Sensitivity tests suggest that the magnitude of the impact of heterogeneous processes strongly depends on aerosol concentration and the surface uptake coefficients used in the box model. However, the impact of temperature on heterogeneous chemical processes is considerably less. The “renoxification” of HNO₃ will affect the components of the troposphere such as nitrogen oxide and ozone.

Graphical abstract

Keywords

Box model; Dust; BC; Sea salt; Heterogeneous chemistry

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