Effect of calcining temperature and time on the characteristics of Sb-doped SnO2 nanoparticles synthesized by the sol

Zhong, X., Yang, B., Zhang, X., Jia, J., & Yi, G. (2012). Effect of calcining temperature and time on the characteristics of Sb-doped SnO2 nanoparticles synthesized by the sol–gel method. Particuology, 10(3), 365–370. https://doi.org/10.1016/j.partic.2011.09.005

Effect of calcining temperature and time on the characteristics of Sb-doped SnO₂ nanoparticles synthesized by the sol–gel method

Xiaohua Zhong ^{a b}, Baoping Yang ^b, Xiaoliang Zhang ^a, Junhong Jia ^a, Gewen Yi ^a *

a State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China

10.1016/j.partic.2011.09.005

Volume 10, Issue 3, June 2012, Pages 365-370

Received 22 December 2010, Revised 25 August 2011, Accepted 22 September 2011, Available online 9 January 2012.

E-mail: gwyi@licp.cas.cn

Highlights

► Calcining temperature has a dominant effect on the crystallite size, crystallinity, lattice distortion ratios and resistivity of the Sb-doped SnO₂ (ATO).

► The ATO nanoparticles calcined at 1000 °C for 3.0 h possess the lowest resistivity of 10.18 Ω cm.

Abstract

Spherical Sb-doped SnO₂ (ATO) nanoparticles were synthesized by the sol–gel route, employing SnCl₄·5H₂O and SbCl3 as precursors in an ethanol solution. The influences of the calcining temperature and calcining time on the crystallite size, crystallinity, lattice parameters, lattice distortion ratio and the resistivity of the ATO nanoparticles were synthetically investigated. The results suggested that the ATO nanoparticles were crystallized in a tetragonal cassiterite structure of SnO₂ with a highly (1 1 0)-plane-preferred orientation. The calcining temperature had a dominating effect on the crystallite size, crystallinity, lattice distortion ratios and resistivity of the ATO. As the calcining temperature increased, the average crystallite size increased, the crystallinity was promoted accompanied by a decrease in the lattice distortion ratio and a corresponding decrease in the resistivity of the ATO. X-ray diffraction (XRD) and Fourier transform infrared spectrophotometer (FTIR) analysis revealed that Sb ions could not entirely supplant the Sn ions in the SnO₂ lattice for a calcining time of less than 0.5 h, even at a calcining temperature of 1000 °C. The ATO nanoparticles calcined at 1000 °C for 3.0 h possessed the lowest resistivity of 10.18 Ω cm.

Graphical abstract

Keywords

Sb-doped SnO₂ (ATO); Calcining; Characteristics; Sol–gel method

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