Volume 10 Issue 4
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Yuan, J., An, Z., Li, B., & Zhang, J. (2012). Facile aqueous synthesis and thermal insulating properties of low-density glass/TiO2 core/shell composite hollow spheres. Particuology, 10(4), 475–479. https://doi.org/10.1016/j.partic.2011.08.005
Facile aqueous synthesis and thermal insulating properties of low-density glass/TiO2 core/shell composite hollow spheres
Jing Yuan a b, Zhenguo An a, Bing Li a, Jingjie Zhang a *
a Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b Graduate School of the Chinese Academy of Sciences, Beijing 100049, China
10.1016/j.partic.2011.08.005
Volume 10, Issue 4, August 2012, Pages 475-479
Received 3 May 2011, Revised 22 August 2011, Accepted 30 August 2011, Available online 12 April 2012.
E-mail: jjzhang@mail.ipc.ac.cn

Highlights

► TiO2 particles can grow on hollow glass microspheres by chemical precipitation. 

► The resulting low-density (0.40 g/cm3) core/shell composite possessed low conductivity coefficient and emissivity in the infrared region.

Abstract

Anatase TiO2 shells assembled on hollow glass microspheres (HGM) with tunable morphologies were successfully prepared through a controllable chemical precipitation method with urea as the precipitator. Thus, glass/TiO2 core/shell composite hollow spheres with low particle density (0.40 g/cm3) were fabricated. The phase structures, morphologies, particle sizes, shell thicknesses, and chemical compositions of the composite microspheres were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The morphology of the TiO2 shell can be tailored by properly monitoring the reaction system component and parameters. The probable growth mechanism and fabrication process of the core/shell products involving the nucleation and oriented growth of TiO2 nanocrystals on hollow glass microspheres was proposed. A low infrared radiation study revealed that the radiation properties of the products are greatly influenced by the unique product shell structures. A thermal conductivity study showed that the TiO2/HGM possess low thermal conductivity that is similar to that of the pristine HGMs. This work provides an additional strategy to prepare low-density thermal insulating particles with tailored morphologies and properties.

Graphical abstract
Keywords
Hollow glass microspheres; TiO2; Core/shell; Emissivity; Thermal conductivity