Emissions of polycyclic aromatic hydrocarbons from coking industries in China--颗粒学报PARTICUOLOGY

Mu, L., Peng, L., Cao, J., He, Q., Li, F., Zhang, J., Liu, X., & Bai, H. (2013). Emissions of polycyclic aromatic hydrocarbons from coking industries in China. Particuology, 11(1), 86–93. https://doi.org/10.1016/j.partic.2012.04.006

Emissions of polycyclic aromatic hydrocarbons from coking industries in China

Ling Mu ^a, Lin Peng ^a *, Junji Cao ^b, Qiusheng He ^c, Fan Li ^d, Jianqiang Zhang ^a, Xiaofeng Liu ^a, Huiling Bai ^a

a College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
b SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi’an 710075, China
c School of Environment and Safety, Taiyuan University of Science and Technology, Taiyuan 030024, China
d Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China

10.1016/j.partic.2012.04.006

Volume 11, Issue 1, February 2013, Pages 86-93

Received 30 October 2011, Revised 29 December 2011, Accepted 26 April 2012, Available online 9 August 2012.

E-mail: plin123@eyou.com

Highlights

► PAHs in the stack flue gas are dominated in the gas phase.

► Nap, AcPy, Flu, PA and AnT are the most abundant PAHs in coking process.

► PAH pollution from coal charging stage is most serious in coking process.

► PAH emission factors are estimated for charging coal and pushing coke stages.

Abstract

This study set out to assess the characteristics of polycyclic aromatic hydrocarbon (PAH) emission from coking industries, with field samplings conducted at four typical coke plants. For each selected plant, stack flue gas samples were collected during processes that included charging coal into the ovens (CC), pushing coke (PC) and the combustion of coke-oven gas (CG). Sixteen individual PAHs on the US EPA priority list were analyzed by gas chromatography/mass spectrometry (GC/MS). Results showed that the total PAH concentrations in the flue gas ranged from 45.776 to 414.874 μg/m³, with the highest emission level for CC (359.545 μg/m³). The concentration of PAH emitted from the CC process in CP1 (stamp charging) was lower than that from CP3 and CP4 (top charging). Low-molecular-weight PAHs (i.e., two- to three-ring PAHs) were predominant contributors to the total PAH contents, and Nap, AcPy, Flu, PhA, and AnT were found to be the most abundant ones. Total BaPeq concentrations for CC (2.248 μg/m³) were higher than those for PC (1.838 μg/m³) and CG (1.082 μg/m³), and DbA was an important contributor to carcinogenic risk as BaP in emissions from coking processes. Particulate PAH accounted for more than 20% of the total BaPeq concentrations, which were significantly higher than the corresponding contributions to the total PAH mass concentration (5%). Both particulate and gaseous PAH should be taken into consideration when the potential toxicity risk of PAH pollution during coking processes is assessed. The mean total-PAH emission factors were 346.132 and 93.173 μg/kg for CC and PC, respectively.

Graphical abstract

Keywords

PAH; Coking; Stack flue gas; Emission factor

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