A novel coated-particle design and fluidized-bed chemical vapor deposition preparation method for fuel-element identification in a nuclear reactor--颗粒学报PARTICUOLOGY

Liu, R., Liu, M., Shao, Y., Chen, X., Ma, J., & Liu, B. (2017). A novel coated-particle design and fluidized-bed chemical vapor deposition preparation method for fuel-element identification in a nuclear reactor. Particuology, 31, 35-41. https://doi.org/10.1016/j.partic.2016.05.009

A novel coated-particle design and fluidized-bed chemical vapor deposition preparation method for fuel-element identification in a nuclear reactor

Rongzheng Liu, Malin Liu ^*, Youlin Shao, Xiaotong Chen, Jingtao Ma, Bing Liu

Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, Tsinghua University, Beijing 100084, China

10.1016/j.partic.2016.05.009

Volume 31, April 2017, Pages 35-41

Received 1 May 2015, Revised 23 June 2015, Accepted 17 May 2016, Available online 20 September 2016, Version of Record 9 March 2017.

E-mail: liumalin@tsinghua.edu.cn

Highlights

• A novel coated particle structure design used in nuclear power plant was proposed.

• High-density SiC layer was coated on particle containing cobalt element.

• An inner high-density SiC-Co_xSi layer was obtained by a modified FB-CVD method.

• The new particle design could prevent the formation and diffusion of cobalt in coating process.

• The coated particle could maintain structure integrity in extreme high temperature.

Abstract

Particle coating is an important method that can be used to expand particle-technology applications. Coated-particle design and preparation for nuclear fuel-element trajectory tracing were focused on in this paper. Particles that contain elemental cobalt were selected because of the characteristic gamma ray spectra of ⁶⁰Co. A novel particle-structure design was proposed by coating particles that contain elemental cobalt with a high-density silicon-carbide (SiC) layer. During the coating process with the high-density SiC layer, cobalt metal was formed and diffused towards the coating, so an inner SiC–Co_xSi layer was designed and obtained by fluidized-bed chemical vapor deposition coupled with in-situ chemical reaction. The coating layers were studied by X-ray diffractometry, scanning electron microscopy, and energy dispersive X-ray spectroscopy techniques. The chemical composition was also determined by inductively coupled plasma optical emission spectrometry. The novel particle design can reduce the formation of metallic cobalt and prevent cobalt diffusion in the coating process, which can maintain safety in a nuclear reactor for an extended period. The experimental results also validated that coated particles maintain their structural integrity at extremely high temperatures (∼1950 °C), which meets the requirements of next-generation nuclear reactors.

Graphical abstract

Keywords

Particle coating; Particle design; Cobalt; Fluidized-bed chemical vapor deposition; Nuclear fuel

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