MoS2-based anode materials for lithium-ion batteries: Developments and perspectives--颗粒学报PARTICUOLOGY

Zhao, L., Wang, Y., Wei, C., Huang, X., Zhang, X., & Wen, G. (2024). MoS2-based anode materials for lithium-ion batteries: Developments and perspectives. Particuology, 87, 240-270. https://doi.org/10.1016/j.partic.2023.08.009

MoS₂-based anode materials for lithium-ion batteries: Developments and perspectives

Lianyu Zhao ^{a 1}, Yishan Wang ^{a 1 *}, Chuncheng Wei ^a, Xiaoxiao Huang ^b *, Xueqian Zhang ^a *, Guangwu Wen ^a

a School of Materials Science and Engineering, Shandong University of Technology, Zibo, 255000, China
b School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China

10.1016/j.partic.2023.08.009

Volume 87, April 2024, Pages 240-270

Received 15 June 2023, Revised 2 August 2023, Accepted 9 August 2023, Available online 4 September 2023, Version of Record 22 September 2023.

E-mail: wyslg@sdut.edu.cn; swliza@hit.edu.cn; zhangxueqian@sdut.edu.cn

Highlights

• Summarized how to distinguish metallic phase and semiconductor phase of MoS₂.

• Four methods of preparing MoS₂-based materials are summarized.

• Study of MoS₂ lithium storage mechanism using DFT calculations and other methods.

• MoS₂ defect engineering was studied to adjust its physicochemical properties.

• Emerging applications of MoS₂-based electrode materials in LIBs.

Abstract

In recent years, significant progress has been achieved in the creation of innovative functional materials for energy storage and conversion. Due to their distinct physicochemical characteristics, ultrathin nanosheets composed of common layered transition metal sulfide materials (MoS₂) have demonstrated promise as high-capacity anode materials for lithium-ion batteries (LIBs). Nevertheless, their practical application is severely limited by the tendency of monolayer nanosheets to restack due to strong van der Waals forces, dramatic volume changes during successive cycles, and low intrinsic conductivity. Recent research advances have shown that composite structures and nanowire morphologies with specific morphologies effectively overcome these issues. This paper reviews the recent research progress on molybdenum disulfide-based composites as anode materials for LIBs and discusses in detail the structural characteristics of pure molybdenum disulfide and other composite forms of molybdenum disulfide. In addition, the phase engineering, defect engineering, and lithium storage mechanisms of molybdenum disulfide and the synthesis of molybdenum disulfide-based nanocomposites by different preparation methods are focused on. Finally, we review the design (structure), recent developments, and challenges of novel anode materials and consider their electrochemical performance in Li-ion batteries.

Graphical abstract

Keywords

Lithium-ion battery; MoS₂-Based anode composites; Synthesis methods; Defect engineering; Lithium storage mechanism

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